Wanted to give an update, I destroyed my Raidz2 for the VMware Storage, added six more 300GB SAS drives (for total of 24 drives) and made 12 vdev with each vdev being mirrored.
I also installed second LSI card, took my two Intel x25-e 64GB SSD drives, added them to the new pool in a mirror and put the log/zil onto it. Since I’m using iscsi I went ahead and used the command zfs set sync=always on the pool. The reason I did this was because my storage controller 10G nic failed after two years, which caused a couple domain controllers to corrupt, wasn’t a big deal, restored from backups and everything was fine again (I do backups twice a day.) I have purchase a second 10G switch and now have two 10G nic’s installed in the storage controller, this way I can go back to sync=disabled if I want.
I’m also excited to say I have bought another storage array, the Supermicro SuperChassis CSE-847E16-R1K28LPB which has 36 HDD bays. I did this because last week I officially filled the entire first Supermicro storage chassis 24 bay all with 300GB SAS drives and the second Supermicro storage chassis 24 bay all with 3TB drives. Need more room to expand. :D