Yes, with a but. ZFS doesn't function like a Drobo, so while you can add space by adding drives, you can't change the arrangement of the drives. For example, if you start with 3 drives in RAIDZ (2 function as data, 1 as parity), you can add 2 more drives in a mirror arrangement (effectively 1 data, 1 backup). But, you can't add those 2 drives to the original 3 to get a 5 disk RAIDZ (4 data and 1 parity).
Basically, once you create a group (VDEV) of drives, you can create more VDEVs that will all live under a pool, but you can't change the number of drives in an existing VDEV, without destroying and recreating that VDEV.